A review of foam fractionation for the removal of per- and polyfluoroalkyl substances (PFAS) from aqueous matrices

The detection of per- and polyfluoroalkyl substances (PFAS) in aqueous matrices is an emerging environmental concern due to their persistent, bioaccumulative and toxic properties. Foam fractionation has emerged as a viable method for removing and concentrating PFAS from aqueous matrices. The method exploits the surface-active nature of the PFAS to adsorb at the air-liquid interfaces of rising air bubbles, resulting in foam formation at the top of a foam fractionator. The removal of PFAS is then achieved through foam harvesting. Foam fractionation has gained increasing attention owing to its inherent advantages, including simplicity and low operational costs. The coupling of foam fractionation with destructive technologies could potentially serve as a comprehensive treatment train for future PFAS management in aqueous matrices. The PFAS-enriched foam, which has a smaller volume, can be directed to subsequent destructive treatment technologies. In this review, we delve into previous experiences with foam fractionation for PFAS removal from various aqueous matrices and critically analyse their key findings. Then, the recent industry advancements and commercial projects that utilise this technology are identified. Finally, future research needs are suggested based on the current challenges. [Display omitted] •Foam fractionation can effectively remove PFAS from aqueous matrices.•Lower removal is usually reported for short-chain PFAS.•PFAS removal can be enhanced through optimising operating strategies.•Recovery and enrichment of PFAS are crucial for subsequent destructive treatment.•Future studies should focus on improving scalability and reducing capital costs.