Rhodium-Catalyzed [7 + 1] Cycloaddition of Exocyclic 1,3-Dienylcyclopropanes and Carbon Monoxide

A rhodium-catalyzed [7 + 1] reaction of exocyclic 1,3-dienylcyclopropanes and carbon monoxide has been developed to synthesize eight-membered carbocycle-embedded bicyclic and tricyclic molecules. In addition, ab initio calculations were conducted to reveal the reaction mechanism.

Bibliographische Detailangaben

Veröffentlicht in:	Organic letters 2023-12, Vol.25 (49), p.8829-8833
Hauptverfasser:	Huang, Zhiqiang, Wang, Xin, Jin, Yi, Wang, Zuwei, Yu, Zhi-Xiang
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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