Rhodium-Catalyzed [7 + 1] Cycloaddition of Exocyclic 1,3-Dienylcyclopropanes and Carbon Monoxide
A rhodium-catalyzed [7 + 1] reaction of exocyclic 1,3-dienylcyclopropanes and carbon monoxide has been developed to synthesize eight-membered carbocycle-embedded bicyclic and tricyclic molecules. In addition, ab initio calculations were conducted to reveal the reaction mechanism.
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| Veröffentlicht in: | Organic letters 2023-12, Vol.25 (49), p.8829-8833 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A rhodium-catalyzed [7 + 1] reaction of exocyclic 1,3-dienylcyclopropanes and carbon monoxide has been developed to synthesize eight-membered carbocycle-embedded bicyclic and tricyclic molecules. In addition, ab initio calculations were conducted to reveal the reaction mechanism. |
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| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/acs.orglett.3c03471 |