Selective detection of ionic liquid fluorescence probes for visual colorimetry of different metal ions

At present, the fast distinction of different metal ions in pure water media is not only a great challenge, but also drives the protection of water quality in environmental water bodies. In this paper, a novel ionic liquid fluorescent probe Glycolic Acid-L-Arginine (GA-L-Arg) was rationally created and designed through an in-depth study of ionic liquids. It is also used as an innovative multi-ion fluorescent probe for colorimetric detection and separate identification of Fe3+ and Co2+ in aqueous solutions of various metal ions. GA-L-Arg has excellent water solubility due to the strong hydrophilicity of Glycolic Acid and L-Arginine. The probe showed high sensitivity, extremely significant selectivity, and great pH stability for Fe3+ and Co2+ in pure water. The GA-L-Arg structure and the mechanism of Fe3+ and Co2+ detection were analyzed by infrared spectroscopic characterization and quantum chemical calculations. More importantly, the distinct colorimetric partitioning of Fe3+ and Co2+ was performed by the unique extraction of Fe3+ in the presence of the fluorescent probe and buffer solution. [Display omitted] •Both the probe itself and the detection process have strong pH stability.•Fe3+ and Co2+ can be selectively detected in aqueous solutions where multiple metal ions coexist.•The probe can clearly distinguish Fe3+ - CO2+ coexistence solutions by selective extraction.•The probe can adjust the extraction time of Fe3+ by pH.•The probe structure and detection mechanism were analyzed by quantum chemical calculations and infrared spectroscopy.