Porous Carbon Foam with Carbon Nanotubes as Cathode for Li−CO2 Batteries

With the extensive use of fossil fuels, the ever‐increasing greenhouse gas of mainly carbon dioxide emissions will result in global climate change. It is of utmost importance to reduce carbon dioxide emissions and its utilization. Li−CO2 batteries can convert carbon dioxide into electrochemical energy. However, developing efficient catalysts for the decomposition of Li2CO3 as the discharge product represents a challenge in Li−CO2 batteries. Herein, we demonstrate a carbon foam composite with growing carbon nanotube by using cobalt as the catalyst, showing the ability to enhance the decomposition rate of Li2CO3, and thus improve the electrochemical performance of Li−CO2 batteries. Benefiting from its abundant pore structure and catalytic sites, the as‐assembled Li−CO2 battery exhibits a desirable overpotential of 1.67 V after 50 cycles. Moreover, the overpotentials are 1.05 and 2.38 V at current densities of 0.02 and 0.20 mA cm−2, respectively. These results provide a new avenue for the development of efficient catalysts for Li−CO2 batteries. Porous carbon foam with carbon nanotubes were elaborately designed and fabricated by using cobalt as the catalyst and utilized as cathode for Li−CO2 battery. The unique structure can enhance the decomposition rate of lithium carbonate, and thus improve the electrochemical performance of Li−CO2 battery.