Integrated Laser Additive Manufacturing of α-Al2O3 Nanoparticle-Seeded β/γ’ Ni-Al Intermetallic Alloy with Enhanced High-Temperature Oxidation Performance
The oxidation of β-NiAl at high temperatures leads to the preferential formation of metastable alumina, such as θ-Al2O3, which exhibits a significantly faster growth rate compared to stable α-Al2O3. However, our recent research has shown that through the use of the surface-dispersing nanoparticles (...
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Veröffentlicht in: | Materials 2023-11, Vol.16 (22), p.7205 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The oxidation of β-NiAl at high temperatures leads to the preferential formation of metastable alumina, such as θ-Al2O3, which exhibits a significantly faster growth rate compared to stable α-Al2O3. However, our recent research has shown that through the use of the surface-dispersing nanoparticles (NPs) of metal oxides with a hexagonal closed pack (hcp), such as α-Al2O3, the thermal growth of α-Al2O3 can be facilitated. The present study employed laser additive manufacturing (LAM) to develop an integrated α-Al2O3 NPs surface-seeded two-phase intermetallic alloy comprising brittle β-NiAl and tougher γ’-Ni3Al, which demonstrated better comprehensive mechanical properties. It was found that seeding the α-Al2O3 NPs promoted the early stage growth of α-Al2O3 on both β and γ’ phases during oxidation in air at 1000 °C. This led to a decrease in the oxidation rate but an enhancement in adhesion of the formed alumina scale in comparison to the naked β/γ’ two-phase alloy. The reasons for this result were interpreted. |
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ISSN: | 1996-1944 1996-1944 |
DOI: | 10.3390/ma16227205 |