Synthesis of Alkyl and Aryl Boronate Esters via CeO2-Catalyzed Borylation of Alkyl and Aryl Electrophiles Including Alkyl Chlorides

A recyclable protocol using a CeO2-nanorod catalyst for borylation of alkyl halides with B2pin2 (pin = OCMe2CMe2O) is reported. A wide range of synthetically useful alkyl boronate esters are readily obtained from primary and secondary alkyl electrophiles, including unactivated alkyl chlorides, demon...

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Veröffentlicht in:Journal of organic chemistry 2023-12, Vol.88 (23), p.16270-16279
Hauptverfasser: Bhawar, Ramesh, Saini, Suresh, Patil, Kiran S, Nagaraju, D H, Bose, Shubhankar Kumar
Format: Artikel
Sprache:eng
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