Advances in Difunctionalization of Olefins with Diorganyl Dichalcogenides

Organochalcogen molecules have extensive applications in various fields. They serve as pharmaceuticals, ligands, organocatalysts, agrochemicals, and other functional materials. Difunctionalization of olefins, which belong to a class of multicomponent reactions, is a successful technique for introducing two functional moieties in a single‐step reaction, both in terms of atom economy and step economy. The difunctionalization of olefins with diorganyl dichalcogenides may effectively increase the molecular complexity, which has achieved significant advancements in recent decades. This article describes recent advancements in the difunctionalization of olefins with diorganyl diselenides and diorganyl disulfides. The difunctionalization of olefins with diorganyl dichalcogenides may effectively increase the molecular complexity, which has undergone significant advancements in recent decades. This review describes recent advancements in the difunctionalization of olefins with diorganyl diselenides and diorganyl disulfides.