Determination of gibbs energy of formation of Ni-B-O system by electromotive force measurement using solid electrolyte

Determination of gibbs energy of formation of Ni-B-O system by electromotive force measurement using solid electrolyte

The standard Gibbs energies of formation of Ni3B, Ni2B, o-Ni4B3(Ni0.586B0.414), m-Ni4B3(Ni0.564B0.436), NiB, and Ni3B2O6 of the Ni-B-O system have been determined by measuring electromotive forces of galvanic cells using a Y2O3-stabilized ZrO2 solid oxide electrolyte.

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Veröffentlicht in:Metallurgical and materials transactions. B, Process metallurgy and materials processing science Process metallurgy and materials processing science, 2006-08, Vol.37 (4), p.607-613
Hauptverfasser: YAMAMOTO, Hiroaki, MORISHITA, Masao, MIYATA, Akio, KOYAMA, Koichiro
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
Exact sciences and technology
Metals. Metallurgy
Production of metals
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Zusammenfassung:The standard Gibbs energies of formation of Ni3B, Ni2B, o-Ni4B3(Ni0.586B0.414), m-Ni4B3(Ni0.564B0.436), NiB, and Ni3B2O6 of the Ni-B-O system have been determined by measuring electromotive forces of galvanic cells using a Y2O3-stabilized ZrO2 solid oxide electrolyte.
ISSN:1073-5615
1543-1916
DOI:10.1007/s11663-006-0044-5