Efficient Fenton-like degradation of tetracycline by stalactite-like CuCo-LDO/CN catalysts: The overlooked contribution of dissolved oxygen

In the Fenton-like processes, the resources that exist in the system itself (e.g., dissolved oxygen, electron-rich pollutants) are often overlooked. Herein, a novel CuCo-LDO/CN composite catalyst with a strong “metal-π” effect was fabricated by in situ calcination which could activate dissolved oxygen to generate active oxygen species and degrade the electron-rich pollutants directly. The CuCo-LDO/CN (1:10) with the largest specific surface aera, most C–O-M bonds and least oxygen vacancies exhibited the best catalytic performance for tetracycline (TC)degradation (TC removal efficiency 93.2% and mineralization efficiency 40%, respectively, after 40 min at neutral pH) compared to CuCo-LDO and other CuCo-LDO/CN composite catalysts. In the absence of H2O2, dissolved oxygen could be activated by the catalyst to generate O2·−and ·OH, which contributed to approximately 20.7% of TC degradation, providing a faster and cost-effective way for TC removal from wastewater. While in the presence of H2O2, it was activated by CuCo-LDO/CN to generate·OH as the dominant reactive oxygen species and meanwhile TC transferred electrons to H2O2 through C–O-M bonds, accelerating the Cu+/Cu2+ and Co2+/Co3+ redox cycles. The possible degradation pathways of TC were proposed, and the environmental hazard of TC is greatly mitigated according to toxicity prediction. Schematic diagram of the degradation of TC (a) in the absence and (b) presence of H2O2. [Display omitted] •CuCo-LDO/CN was prepared by calcination with a strong “metal-π” effect.•CuCo-LDO/CN (1:10) with the largest SSA and most C–O-M bonds exhibited the best catalytic performance.•Dissolved oxygen could be activated by CuCo-LDO/CN to O2·- and ·OH.•The overall toxicity of TC was effectively alleviated after degradation.