Skeletal rearrangement of a boron-containing annulenic molecule into a macrocycle bridged by an electronically stabilized boron cation
An annulenic molecule containing a three-coordinate chloroborane moiety, which exhibits a borane-olefin proximity effect, undergoes a skeletal rearrangement upon chloride abstraction, to generate a three-dimensional macrocyclic molecule featuring a borocenium (η 5 -cyclopentadienyl–B + –R) structure...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2023-11, Vol.59 (91), p.13635-13638 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | An annulenic molecule containing a three-coordinate chloroborane moiety, which exhibits a borane-olefin proximity effect, undergoes a skeletal rearrangement upon chloride abstraction, to generate a three-dimensional macrocyclic molecule featuring a borocenium (η
5
-cyclopentadienyl–B
+
–R) structure. |
|---|---|
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/d3cc04830f |