Inelastic light scattering of hydrogen containing open-cage fullerene ATOCF

Inelastic light scattering of hydrogen containing open-cage fullerene ATOCF

We report Raman measurements on Aza‐Thia Open‐Cage Fullerene (ATOCF) containing hydrogen molecules. We analyze the spectral bands of empty and H2‐filled ATOCF and compare them with Raman spectra ofpristine C60. We find a large number of additional bands due to the lower symmetry of ATOCF and detect...

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Veröffentlicht in:Physica Status Solidi (b) 2005-10, Vol.242 (12), p.R106-R108
Hauptverfasser: Rafailov, P. M., Thomsen, C., Bassil, A., Komatsu, K., Bacsa, W.
Format: Artikel
Sprache:eng
Schlagworte:
63.22.+m
78.30.Na
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Lattice dynamics
Phonons and vibrations in crystal lattices
Physics
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Beschreibung
Zusammenfassung:We report Raman measurements on Aza‐Thia Open‐Cage Fullerene (ATOCF) containing hydrogen molecules. We analyze the spectral bands of empty and H2‐filled ATOCF and compare them with Raman spectra ofpristine C60. We find a large number of additional bands due to the lower symmetry of ATOCF and detect the hydrogen stretching vibration of the caged H2 molecules. Depending on their environment significant band broadening is observed. ATOCF molecule containing H2. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
ISSN:0370-1972
1521-3951
DOI:10.1002/pssb.200541168