ArI(NTf2)2: the boundary of oxidative capacity for ArIL2?

ArI(NTf2)2: the boundary of oxidative capacity for ArIL2?

Synthesis and crystallographic characterization of NO2–C6H4–I(NTf2)2 (NTf2 = bistriflimide) is reported. Experimental results find that this compound can perform oxidation reactions that ArI(OTf)2 is unable to and theoretical analysis indicates Ar–I(NTf2)2 is the most oxidizing in the ArIL2 class of...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-11, Vol.59 (89), p.13340-13343
Hauptverfasser: Barwise, Lachlan, Bennetts, Jason D, White, Keith F, Dutton, Jason L
Format: Artikel
Sprache:eng
Schlagworte:
Crystallography
Nitrogen dioxide
Oxidation
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Zusammenfassung:Synthesis and crystallographic characterization of NO2–C6H4–I(NTf2)2 (NTf2 = bistriflimide) is reported. Experimental results find that this compound can perform oxidation reactions that ArI(OTf)2 is unable to and theoretical analysis indicates Ar–I(NTf2)2 is the most oxidizing in the ArIL2 class of compounds known and may also be the most oxidizing compound in the class practically possible.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc04563c