Photo-controllable binding and release of HP2O73− using an azobenzene based smart macrocycle

Photo-controllable binding and release of HP2O73− using an azobenzene based smart macrocycle

Herein, we describe the design and synthesis of an unusual azobenzene-bearing macrocycle 1, whose trans isomer was found able to 100% transform into its cis configuration under photoirradiation, for selectively recognizing HP2O73− with reversibly photo-controllable binding and release properties.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-10, Vol.59 (87), p.12994-12997
Hauptverfasser: Xiong, Shenglun, Zhang, Yi, Jiang, Yunqi, Wang, Fei, Zhou, Wei, Li, Aimin, Zhang, Qinpeng, Wang, Qiuan, He, Qing
Format: Artikel
Sprache:eng
Schlagworte:
Azo compounds
Binding
Controllability
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Zusammenfassung:Herein, we describe the design and synthesis of an unusual azobenzene-bearing macrocycle 1, whose trans isomer was found able to 100% transform into its cis configuration under photoirradiation, for selectively recognizing HP2O73− with reversibly photo-controllable binding and release properties.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc03608a