Triboelectric charging between polytetrafluoroethylene and metals

Measurements were obtained on charge exchange processes occurring between small metal ballistic pellets and a polytetrafluoroethylene (PTFE) tube. Lead pellets of 5.5-mm diameter were propelled at a range of speeds through PTFE tubes of different lengths by compressed carbon dioxide. The charge incurred by the pellets and the tube was compared with the charge observed on copper and lead spheres rolled through the tube, driven by gravity. In all experiments, the charge on the moving pellet was measured with a Faraday cup. The experiments determined the effect of pellet speed on the magnitude of the charge accumulated on the pellet and on the PTFE tube. Sectioned shielding on the PTFE tube allowed the determination of surface charge distribution along its length by means of an electrometer. It was observed that the charge also depended on the work functions of the materials involved (lead, copper, PTFE). The charge on the pellets was found to range from +0.5/spl times/10/sup -8/ to +3.0/spl times/10/sup -8/ C, for pellet speeds from 10 to 80 m/spl middot/s/sup -1/. The reproducibility of results is discussed and comment provided on the degree of charge imbalance observed.