Understanding the origins of and influences on precipitation major ion chemistry on the Island of Oʻahu, Hawaiʻi

Precipitation is the primary groundwater source for the Island of Oʻahu, Hawaiʻi, USA, and is an important source of terrestrial nutrients. Since Pacific Islands are particularly vulnerable to the impacts of climate change, they are important venues for studying the controls on and fluctuations in precipitation chemistry. Spatial variations in some of the dissolved rainfall ions can also be of value as natural geochemical tracers in examining surface and groundwater flow. This study collected and chemically analyzed bulk precipitation from 20 sites across the Island of Oʻahu approximately quarterly between April 2018 and August 2021. The new precipitation chemistry data were integrated with previously published precipitation data to characterize major ion composition and examine the atmospheric processes controlling inorganic ion deposition. Linear regression and multivariate analysis were used to quantify the relationships among major ions and to assess the impacts of various environmental and meteorological factors on precipitation chemistry. Ordinary kriging and inverse distance weighted interpolations were conducted to help visualize spatial variations in major ion deposition. The results clearly indicate that ocean sea spray is the primary driver of precipitation inorganic chemistry, with marine sea salt aerosols accounting for more than 90% of the measured ion load. However, they also show that various weather patterns and nutrient sources impact inorganic deposition. Most notably, upper atmospheric transport of Asian continental dust during Hawaiian wet seasons, Ca 2+ from local sedimentary deposits, and anthropogenic K + from agricultural activity appear to be substantial non-marine deposition sources. This study synthesizes data from multiple sources into the most spatially and topographically diverse precipitation collector network on Oʻahu to date. The findings from this effort help establish a baseline for assessing future fluctuations in inorganic ion deposition and lay important groundwork for examining connections between precipitation and groundwater chemistry within the study area.