Effect of fluorine on Li[Ni1/3Co1/3Mn1/3]O2-zFz as lithium intercalation material

Li[Ni1/3Co1/3Mn1/3]O2-zFz (x=0-0.15) were synthesized via a co-precipitation followed by a high-temperature heat treatment. Though the initial discharge capacities of Li[Ni1/3Co1/3Mn1/3]O2-zFz (x=0-0.15) is somewhat smaller, capacity retention, rate capability, and thermal stability at highly oxidiz...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Journal of power sources 2005-08, Vol.146 (1-2), p.602-605
Hauptverfasser:	KIM, Gil-Ho, KIM, Myung-Hoon, MYUNG, Seung-Taek, YANG KOOK SUN
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Li[Ni1/3Co1/3Mn1/3]O2-zFz (x=0-0.15) were synthesized via a co-precipitation followed by a high-temperature heat treatment. Though the initial discharge capacities of Li[Ni1/3Co1/3Mn1/3]O2-zFz (x=0-0.15) is somewhat smaller, capacity retention, rate capability, and thermal stability at highly oxidized state were significantly improved comparing to the undoped Li[Ni1/3Co1/3Mn1/3]O2. Fluorine substitution for oxygen made it possible to use the cathode material at 4.6 V cut-off limit.
ISSN:	0378-7753 1873-2755
DOI:	10.1016/j.jpowsour.2005.03.045