SO42− ions as a nucleophilic reagent: straightforward electrochemical access to organosulfates

SO42− ions as a nucleophilic reagent: straightforward electrochemical access to organosulfates

An electrooxidation direct difunctionalization of alkynes with sulfonyl hydrazides has been developed for the construction of sulfonyl alkenyl sulfates in the absence of metal catalysts and a stoichiometric amount of oxidants. Notably, it is the first example to verify that SO42− ions can act as a n...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-10, Vol.59 (81), p.12164-12167
Hauptverfasser: Chen, Li, Chen, Zhuo, Xue-Yang, Guo, Li-Rong, Wen, Li, Ming, Lin-Bao, Zhang
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes
Hydrazides
Oxidizing agents
Reagents
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Zusammenfassung:An electrooxidation direct difunctionalization of alkynes with sulfonyl hydrazides has been developed for the construction of sulfonyl alkenyl sulfates in the absence of metal catalysts and a stoichiometric amount of oxidants. Notably, it is the first example to verify that SO42− ions can act as a nucleophilic reagent for the preparation of organosulfates.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc03960a