Effect of the magnetic core in alginate/gum composite on adsorption of divalent copper, cadmium, and lead ions in the aqueous system

The change of composition of an adsorbent material has been widely used as a method to increase its adsorption capacity, particularly concerning adsorbents made of polysaccharides. Introducing magnetic adsorbents into contaminated water treatment systems is a highly promising strategy, as it promotes the metal ions removal from water. Considering this, gum Arabic (GA) was associated with alginate (Alg), when magnetite nanoparticles were present or absent, to produce beads that were utilised to take up Cu(II), Cd(II), and Pb(II) from aqueous solution. After a complete characterisation (for which Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy, and swelling were used), the adsorption properties were established using batch and column tests. The magnetic beads (MAlg/GA) demonstrated improved adsorption in comparison with the beads made without magnetite (Alg/GA) under the same conditions. In normal adsorption conditions (pH 6.0, 25 °C, 2.5 g L−1 of adsorbent dosage), the highest uptake capacities recorded for the MAlg/GA beads were: for Cu(II), 1.33 mmol g−1; Cd(II), 1.59 mmol g−1; and for Pb(II), 1.43 mmol g−1. The pseudo-second-order kinetics and Langmuir isotherm models provided good fits for the adsorption of these metals. Overall, ion exchange and physical forces led to the uptake of these metals by both Alg/GA and MAlg/GA; moreover, the functional groups on the beads played crucial roles as binding sites. Additionally, it was observed that flow rates of >2 mL min−1 did not produce noticeable changes in uptake levels over the same flow period. It was found that the efficient eluting agent was HNO3 (0.2 M). In some cases, the metals were not removed fully from the used beads during the first five cycles of regeneration and reuse. The results of this investigation show that these beads are efficient adsorbents for the removal of metal ions from spiked well water samples. [Display omitted] •New composite adsorbents were prepared and characterized.•Alginate, Gum Arabic, and magnetite nanoparticles were the precursors.•The composite adsorbed Cu(II), Cd(II), and Pb(II) from water with high efficiency.•Langmuir and Temkin equations fit well with the adsorption isotherms.•Metals bound onto the composite were desorbed with remarkable stability at reuse.