Two and three-dimensional halogen-bonded frameworks: self-assembly influenced by crystallization solvents

Two and three-dimensional halogen-bonded frameworks: self-assembly influenced by crystallization solvents

In this paper, two types of solid phase 2D and 3D XBOFs were selectively constructed from identical building blocks of tetraphenylmethane tetrapyridine derivative and 1,4-diiodotetrafluorobenzene by changing the crystallization solvent. This 3D XBOF is a novel hybrid supramolecular organic framework...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-09, Vol.59 (77), p.1158-11583
Hauptverfasser: Liu, Chuan-Zhi, Wang, Jing-Jing, Yang, Bo, Li, Zhong-Yi, Yan, Meng, Liu, Xin-Ming, Hu, Zhi-Yuan, Liu, Lan-Tao, Li, Zhan-Ting
Format: Artikel
Sprache:eng
Schlagworte:
Crystallization
Self-assembly
Solid phases
Solvents
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Zusammenfassung:In this paper, two types of solid phase 2D and 3D XBOFs were selectively constructed from identical building blocks of tetraphenylmethane tetrapyridine derivative and 1,4-diiodotetrafluorobenzene by changing the crystallization solvent. This 3D XBOF is a novel hybrid supramolecular organic framework with the synergistic control of hydrogen and halogen bonds. Two types of 2D and 3D XBOFs were selectively constructed from identical building blocks by changing the crystallization solvent.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc02981f