Regioselective ortho C–H insertion of N -nitrosoanilines with naphthoquinone carbenes

Regioselective ortho C–H insertion of N -nitrosoanilines with naphthoquinone carbenes

A Rh( iii )-catalyzed ortho C–H migratory insertion of N -nitrosoanilines with naphthoquinone carbenes has been developed. The products were obtained in good yields under mild reaction conditions. Diverse elaborations of the products were explored. This method is valuable for the synthesis of biaryl...

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Veröffentlicht in:Organic & biomolecular chemistry 2023-09, Vol.21 (37), p.7525-7529
Hauptverfasser: Peng, Rui-jun, Chen, Yuan, Zhang, Xue-jing, Yan, Ming
Format: Artikel
Sprache:eng
Schlagworte:
Carbenes
Insertion
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Zusammenfassung:A Rh( iii )-catalyzed ortho C–H migratory insertion of N -nitrosoanilines with naphthoquinone carbenes has been developed. The products were obtained in good yields under mild reaction conditions. Diverse elaborations of the products were explored. This method is valuable for the synthesis of biarylamines and their derivatives.
ISSN:1477-0520
1477-0539
DOI:10.1039/d3ob01104f