Slip-Enhanced Transport by Graphene in the Microporous Layer for High Power Density Proton-Exchange Membrane Fuel Cells

Proton exchange membrane (PEM) fuel cells are a promising and environmentally friendly device to directly convert hydrogen energy into electric energy. However, water flooding and gas transport losses degrade its power density owing to structural issues (cracks, roughness, etc.) of the microporous layer (MPL). Here, we introduce a green material, supercritical fluid exfoliated graphene (s-Gr), to act as a network to effectively improve gas transport and water management. The assembled PEM fuel cell achieves a power density of 1.12 W cm–2. This improved performance is attributed to the reduction of cracks and the slip of water and gas on the s-Gr surface, in great contrast to the nonslip behavior on carbon black (CB). These findings open up an avenue to solve the water and gas transport problem in porous media by materials design with low friction and provide a new opportunity to boost high power density PEM fuel cells.