Releases of microplastics and chemicals from nonwoven polyester fabric-based polyurethane synthetic leather by photoaging

The nonwoven PET fabrics are chemically, mechanically and thermally treated fiber aggregate without weaving, knitting or braiding, which could be used as a base to make polyurethane (PU) synthetic leather through a series of processing. Our research systematically compared the photoaging behaviors of pure non-woven PET base fabric (NPET-P) and PU synthetic leather (nonwoven PET-base fabrics with PU coating, NPET-U), and their possibilities for microplastic fibers (MPFs) generation and chemical transformation in water. NPET-U was photoaged to a higher oxidation degree with higher O/C ratios and more distinct changes in chemical structures. The amount of MPFs released from NPET-U (1.98 × 107 g/fibers) was significantly lower than that from NPET-P (4.76 × 107 g/fibers) after 360 h light irradiation (p value