Tetracycline-adsorbed biochar for solid biofuel usage to achieve waste utilization for environmental sustainability

Biochar is widely used to remove organic pollutants from the environment. Several studies have focused on pollutant removal via biochar adsorption. However, research on the subsequent processing of pollutant-adsorbed biochar is lacking. This study explored the potential of biochar for the adsorption of an aquatic organic pollutant (tetracycline) and its subsequent use as a solid biofuel. These results suggest that corn straw-derived biochar (torrefaction and pyrolysis) is suitable for two-stage utilization to achieve bioresource valorization for environmental sustainability. Tetracycline-adsorbed biochar, particularly biochar pyrolyzed at 600 °C, is suitable for use as a biofuel. The biochar produced via torrefaction (300 °C) and pyrolysis (600 °C) is the optimal choice, with surface area, contact angle, graphitization degree, calorific value, enhancement factor, and upgrading energy index values of 172.48 m2/g, 120.4°, 3.87, 26.983 MJ/kg, 1.58, and 33.72, respectively. This is supported by the results of expense calculation, comprehensive performance analysis, and life-cycle assessment. Overall, the biochar produced in this study is suitable for organic pollutant removal and as solid biofuel; thus, it can be used to realize waste utilization for environmental sustainability. [Display omitted] •Two-stage treatment enhances the adsorption capacity and HHV by 20% and 11.42%.•Pyrolysis process is conducive for biochar HHV and adsorption capacity enhancement.•The HHV of tetracycline-adsorbed biochar ranges at 21.55–26.98 MJ/kg.•Expense calculation and LCA analysis are adopted for biofuel property evaluation.•The optimal solution for tetracycline removal and solid biofuel usage is provided.