MB3P2S10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B6P4S20] T3-supertetrahedra

MB3P2S10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B6P4S20] T3-supertetrahedra

Two new alkaline metal thioboratephosphates, RbB3P2S10 and CsB3P2S10, have been designed and fabricated by the flux method. The two compounds are composed of alkali metal polyhedral and [B6P4S20] T3-supertetrahedral units, and crystallize in I41/a and R3c space groups, respectively. The results enri...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2023-08, Vol.52 (33), p.11401-11406
Hauptverfasser: Zhou, Jiazheng, Su, Xin, Luo, Ling, Li, Junjie, Yu, Feng
Format: Artikel
Sprache:eng
Schlagworte:
Alkali metal compounds
Functional materials
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Zusammenfassung:Two new alkaline metal thioboratephosphates, RbB3P2S10 and CsB3P2S10, have been designed and fabricated by the flux method. The two compounds are composed of alkali metal polyhedral and [B6P4S20] T3-supertetrahedral units, and crystallize in I41/a and R3c space groups, respectively. The results enrich the chemical diversity of chalcogenides, and give insights for the exploration of new functional materials in thioboratephosphates.
ISSN:1477-9226
1477-9234
DOI:10.1039/d3dt01496g