Spatio-temporal variation of groundwater chemistry in the Upper Oti Basin of Ghana

The Oti Basin is located at northeastern part of Ghana. Two major geological formations of Voltaian sedimentary supergroup exist: Kwahu-Morago and Oti-Pendjari groups. A total of 133 groundwater samples and 7 surface water samples were collected for two major seasons, viz. dry season (February, 2020) and wet season (November, 2020), and analysed for cations and anions. This is to determine the sources of ions, including pollutants and the reactions that promote them for sustainable groundwater management. Results of major ions revealed groundwater is potable base on the WHO permissible limits. Wet season nitrate and sulphate were higher than that of dry season, suggesting anthropogenic influence. Pearson’s correlation shows major contributors of total dissolved solids were Mg, Na and HCO 3 with a correlation ( r = 0.439, 0.874 and 0. 945) respectively. In the wet season, major contributors were TH, Mg, Na, SO 4 and HCO 3 with correlation ( r = 0.548, 0.537, 0.856, 0.530 and 0.936) respectively. Gibbs plot suggests chemical weathering and precipitation to be the main contributors to the water chemistry. The dominant hydrochemical facies within the basin for both seasons was Na–K-HCO 3 water type. The plot of Ca 2+ + Mg 2+ vs. HCO3 − + SO4 2− suggests both silicate weathering and ion exchange processes are taking place within the basin. Mineral stability diagrams signify kaolinite as the most stable mineral phase in the groundwater. Chloro-alkaline indices were negative for both seasons leading to base-exchanged softened water production . Consequently, majority of ions evolved from natural geochemical processes whilst nitrate and sulphate presence might be due to anthropogenic sources.