Synergistic effect of excellent carriers separation and efficient high level energy electron utilization on Bi3+-Ce2Ti2O7/ZnIn2S4 heterostructure for photocatalytic hydrogen production

[Display omitted] •CTOZIS and BCTOZIS photocatalyst were synthesized through hydrothermal method.•The H2 evolution rate of BCTOZIS was 7.6 times than that of ZIS.•The HLEEs utilization plays an important role in promoting hydrogen production.•The synergistic effect of Z-type transfer and HLEEs boosts photocatalytic activity. The separation of photogenerated carriers and the efficient utilization of high-level energy electrons (HLEEs) are the key processes for improving the performance of photocatalysts. Herein, Ce2Ti2O7/ZnIn2S4 (CTOZIS) and Bi3+-doped Ce2Ti2O7/ZnIn2S4 (BCTOZIS) photocatalyst were successfully synthesized through hydrothermal method. The photocatalytic hydrogen production of CTOZIS and BCTOZIS was 1233.7 μmol g-1 and 4168.5 μmol g-1 under visible light irradiation (λ ≥ 420 nm) within 5 hours, which was 2.3 and 7.6 times than that of pure ZnIn2S4, respectively. X-ray photoelectron spectroscopy, photoluminescence spectroscopy and electrochemical characterization demonstrated that after Bi3+ doping, the electron-hole pairs recombination of BCTOZIS was inhibited, which may be ascribed to the establishment of a Z-scheme heterojunction and the presence of oxygen vacancy and Ce4+/Ce3+ redox center. The doping of Bi3+ resulted in the adjustment of the valence band position of Ce2Ti2O7 from 1.98 V to 1.92 V. This adjustment enabled direct transfer of HLEEs generated in Ce2Ti2O7 to the conduction band of ZnIn2S4 for hydrogen production with a wavelength below 423 nm. The synergistic effect of conventional Z-scheme electron transfer and the unique utilization of HLEEs boosted the photocatalytic performance of BCTOZIS. This study affords an innovative insight for designing visible-light-driven photocatalysts with high photocatalytic activity.