(1)(2)(1)Sb Mossbauer spectroscopy of 10mol% Sb2Te3 section of pseudo--ternary Sb2Se3--As2Se3--Sb2Te3 glasses
The local environment of antimony atoms in vitreous samples of 10mol% Sb2Te3 section of the Sb2Se3-As2Se3-Sb2Te3 pseudo-ternary has been studied by mean of 121Sb Mossbauer spectroscopy. The Mossbauer parameters (D*C, D*d and D*D) show respectively one environment type for antimony, a decrease of the...
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Veröffentlicht in: | Journal of non-crystalline solids 2005-08, Vol.351 (27-29), p.2329-2332 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The local environment of antimony atoms in vitreous samples of 10mol% Sb2Te3 section of the Sb2Se3-As2Se3-Sb2Te3 pseudo-ternary has been studied by mean of 121Sb Mossbauer spectroscopy. The Mossbauer parameters (D*C, D*d and D*D) show respectively one environment type for antimony, a decrease of the s-electron density and one less distorted local environment of Sb to 50 and 70mol% As2Se3 and one more distorted to 75 and 90mol% As2Se3 on the section 10mol% Sb2Te3. |
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ISSN: | 0022-3093 |
DOI: | 10.1016/j.jnoncrysol.2005.06.011 |