(1)(2)(1)Sb Mossbauer spectroscopy of 10mol% Sb2Te3 section of pseudo--ternary Sb2Se3--As2Se3--Sb2Te3 glasses

The local environment of antimony atoms in vitreous samples of 10mol% Sb2Te3 section of the Sb2Se3-As2Se3-Sb2Te3 pseudo-ternary has been studied by mean of 121Sb Mossbauer spectroscopy. The Mossbauer parameters (D*C, D*d and D*D) show respectively one environment type for antimony, a decrease of the...

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Veröffentlicht in:Journal of non-crystalline solids 2005-08, Vol.351 (27-29), p.2329-2332
Hauptverfasser: Deli, M L, Jumas, J C, Dichi, E, Boigny, D H
Format: Artikel
Sprache:eng
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Zusammenfassung:The local environment of antimony atoms in vitreous samples of 10mol% Sb2Te3 section of the Sb2Se3-As2Se3-Sb2Te3 pseudo-ternary has been studied by mean of 121Sb Mossbauer spectroscopy. The Mossbauer parameters (D*C, D*d and D*D) show respectively one environment type for antimony, a decrease of the s-electron density and one less distorted local environment of Sb to 50 and 70mol% As2Se3 and one more distorted to 75 and 90mol% As2Se3 on the section 10mol% Sb2Te3.
ISSN:0022-3093
DOI:10.1016/j.jnoncrysol.2005.06.011