Study of the stability of n-diamond

Powders of n-diamond can be synthesized by pyrogenation of carbon black and nanometre-sized iron catalyst at atmospheric pressure and at a temperature of l 100 deg C. The stability of n-diamond was investigated with x-ray diffraction, thermal gravimetric analysis and differential thermal analysis. T...

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Veröffentlicht in:Journal of physics. Condensed matter 2004-05, Vol.16 (17), p.2991-2994
Hauptverfasser: Wen, Bin, Li, Tingju, Dong, Chuang, Zhang, Xingguo, Yao, Shan, Cao, Zhiqiang, Wang, Dehe, Ji, Shouhua, Jin, Junze
Format: Artikel
Sprache:eng
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Zusammenfassung:Powders of n-diamond can be synthesized by pyrogenation of carbon black and nanometre-sized iron catalyst at atmospheric pressure and at a temperature of l 100 deg C. The stability of n-diamond was investigated with x-ray diffraction, thermal gravimetric analysis and differential thermal analysis. The results indicated that n-diamond was a metastable phase: it can decompose at room temperature slowly. Thermal decomposition of n-diamond begins at 150DGC and is complete at 400 deg C, and the decomposition of n-diamond was an exothermic reaction.
ISSN:0953-8984
1361-648X
DOI:10.1088/0953-8984/16/17/026