Synthesis of new open-chain alkoxyamines and their evaluation for nitroxide-mediated radical polymerization

New readily available open‐chain alkoxyamines have been synthesized and evaluated as unimolecular initiators for nitroxide‐mediated radical polymerization of styrene and n‐butyl acrylate. The observed moderate control of polymerization is explained by the low thermostability of the parent nitroxide....

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Veröffentlicht in:	Polymer international 2004-08, Vol.53 (8), p.1066-1070
Hauptverfasser:	Nesvadba, Peter, Bugnon, Lucienne, Sift, Rosemarie
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology nitroxide stability nitroxide-mediated polymerization open-chain alkoxyamine Physicochemistry of polymers Polymer industry, paints, wood radical polymerization Technology of polymers
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Beschreibung
Zusammenfassung:	New readily available open‐chain alkoxyamines have been synthesized and evaluated as unimolecular initiators for nitroxide‐mediated radical polymerization of styrene and n‐butyl acrylate. The observed moderate control of polymerization is explained by the low thermostability of the parent nitroxide. Copyright © 2004 Society of Chemical Industry
ISSN:	0959-8103 1097-0126
DOI:	10.1002/pi.1492