A heteroleptic fused bi-cuboctahedral Cu21S2 cluster

A heteroleptic fused bi-cuboctahedral Cu21S2 cluster

A new dicationic cluster, [Cu S {S CN Bu } (C Ph) ] , where the Cu21S2 kernel consists of two S@Cu cuboctahedra sharing a triangular Cu face is reported. Its waist part is bridged by three dithiocarbamate ligands, each in a hexaconnective, hexametallic (μ , μ ) coordination pattern, an unprecedented...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-08, Vol.59 (63), p.9638-9641
Hauptverfasser: Silalahi, Rhone P Brocha, Chiu, Tzu-Hao, Liang, Hao, Kahlal, Samia, Saillard, Jean-Yves, Liu, C W
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
Nanoclusters
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Zusammenfassung:A new dicationic cluster, [Cu S {S CN Bu } (C Ph) ] , where the Cu21S2 kernel consists of two S@Cu cuboctahedra sharing a triangular Cu face is reported. Its waist part is bridged by three dithiocarbamate ligands, each in a hexaconnective, hexametallic (μ , μ ) coordination pattern, an unprecedented feature in Cu nanocluster chemistry.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc02936k