Selective Depolymerization of Lignin Towards Isolated Phenolic Acids Under Mild Conditions

The selective transformation of lignin to value‐added biochemicals (e. g., phenolic acids) in high yields is incredibly challenging due to its structural complexity and many possible reaction pathways. Phenolic acids (PA) are key building blocks for various aromatic polymers, but the isolation of PA...

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Veröffentlicht in:ChemSusChem 2023-10, Vol.16 (20), p.e202300750-n/a
Hauptverfasser: Peng, Wenbo, Bao, Hanxi, Wang, Yigui, Cote, Elizabeth, Sagues, William J, Hagelin‐Weaver, Halena, Gao, Ji, Xiao, Dequan, Tong, Zhaohui
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Sprache:eng
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Zusammenfassung:The selective transformation of lignin to value‐added biochemicals (e. g., phenolic acids) in high yields is incredibly challenging due to its structural complexity and many possible reaction pathways. Phenolic acids (PA) are key building blocks for various aromatic polymers, but the isolation of PAs from lignin is below 5 wt.% and requires harsh reaction conditions. Herein, we demonstrate an effective route to selectively convert lignin extracted from sweet sorghum and poplar into isolated PA in a high yield (up to 20 wt.% of lignin) using a low‐cost graphene oxide‐urea hydrogen peroxide (GO‐UHP) catalyst under mild conditions (
ISSN:1864-5631
1864-564X
DOI:10.1002/cssc.202300750