Process optimization and technoeconomic assessment of biodiesel production by one-pot transesterification of Ricinus communis seed oil

[Display omitted] •Biodiesel was produced from Ricinus communis oil using ionic liquid catalyst.•The biodiesel yield was optimized using Response Surface Methodology.•The one-pot transesterification reaction followed pseudo-first-order kinetics.•The catalyst displayed good stability for three cycles...

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Veröffentlicht in:Bioresource technology 2023-05, Vol.376, p.128880-128880, Article 128880
Hauptverfasser: Sangeetha, Baskaran, Mohana Priya, Srinivasan, Pravin, Ravichandran, Tamilarasan, Krishnamurthi, Baskar, Gurunathan
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Sprache:eng
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Zusammenfassung:[Display omitted] •Biodiesel was produced from Ricinus communis oil using ionic liquid catalyst.•The biodiesel yield was optimized using Response Surface Methodology.•The one-pot transesterification reaction followed pseudo-first-order kinetics.•The catalyst displayed good stability for three cycles of reusability.•The techno-economic analysis and sensitivity analysis were investigated. In the present study, Ricinus communis seed oil with high free fatty acid content was utilized for the one-pot biodiesel production using 1-(2,3-dihydroxy)-propyl-3-methylimidazolium hydroxide, a basic ionic liquid catalyst. The 97.83% biodiesel yield was obtained at the optimized conditions of 6.26 % (w/w) of catalyst concentration, 10.51:1 M ratio of methanol to oil, 57.87 °C temperature and reaction time of 61.01 min. The transesterification of Ricinus communis seed oil to biodiesel exhibited an activation energy of 37.60 kJ/mol. The technoeconomic analysis, the profitability and the sensitivity analysis were investigated for the simulated process design. The technoeconomic analysis reported a total revenue of 20,455,431 $/yr, with gross margins, ROI, payback period, IRR, and NPV of 23.54%, 35.72%, 2.8 years, 28.20%, and 19,287,000 $, respectively. According to the sensitivity analysis, the two most important factors determining the economic viability of the simulated process are Ricinus communis seed oil cost and biodiesel selling price.
ISSN:0960-8524
1873-2976
DOI:10.1016/j.biortech.2023.128880