Organic-inorganic hybrid material. I. Synthesis, characterization, and thermal property of a novel polyhedral cubic silsesquioxane

Hydrosilylation of 2‐chloroethylvinyl ether by octahydridosilsesilsesquioxane catalyzed by hexachloroplatinic acid was carried out to afford a quantitative yield of 3 in its white crystals. Thermogravimetric analysis of Si8O12(CH2CH2OCH2CH2Cl)8 3 revealed that it is reasonably thermally stable. Spec...

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Veröffentlicht in:	Journal of applied polymer science 2004-07, Vol.93 (2), p.907-910
Hauptverfasser:	Dare, Enock O., Olatunji, Gabriel A., Ogunniyi, David S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences cubic-silsesquioxane Exact sciences and technology hybrid materials Physicochemistry of polymers Polymer industry, paints, wood Technology of polymers thermogravimetric analysis
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Hydrosilylation of 2‐chloroethylvinyl ether by octahydridosilsesilsesquioxane catalyzed by hexachloroplatinic acid was carried out to afford a quantitative yield of 3 in its white crystals. Thermogravimetric analysis of Si8O12(CH2CH2OCH2CH2Cl)8 3 revealed that it is reasonably thermally stable. Spectroscopic data and crystal structure were used to justify the integrity, structural and molecular connectivity of the hitherto novel compound. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 907–910, 2004
ISSN:	0021-8995 1097-4628
DOI:	10.1002/app.20530