Reaction Kinetics of Coke and some Carbonaceous Materials with CO2 and Coke Strength after Reaction

The reaction rate per unit mass of wood char was an order of magnitude larger than that of coke and graphite and that of glassy carbon was an order of magnitude smaller than the latter. However, the reaction rate per unit surface area of wood char was smaller than that of graphite. The reaction of coke proceeded homogeneously at temperatures lower than 1373 K, while the reaction was restricted to the surface layer at higher temperatures. The tensile strength of coke after reaction decreased with the reaction degree at 1273 K, but was not changed or even increased at 1573 K. This is due to the fact that at 1573 K the core of the sample was not attacked by CO2 but strengthened by further crystallization.