An Ultrafast, Energy‐Efficient Electrochromic and Thermochromic Device for Smart Windows

Smart windows nowadays undertake the esteemed obligation of reducing energy consumption as well as upgrading living experience. This project aims to devise a smart window that responds to both electricity and heat, with the intention of achieving energy efficiency, privacy preservation, and enhanced decorative attributes. Through the implementation of a novel electrochromic material design, coupled with the optimization of electrochromic devices (ECDs), a high‐performance ECD is obtained, demonstrating coloring/bleaching time of 0.53/0.16 s, a transmittance modulation of 78% (from 99% to 21%), and superior performance in six dimensions. Furthermore, temperature‐responsive units and an ionic liquid are incorporated into the electrolyte system to create a novel thermochromic gel electrolyte with transmittance modulation from 80% to 0%, and excellent thermal insulation (6.4 °C reduction). Ultimately, an electro‐ and thermochromic device is developed, featuring an ultrafast color‐switching speed of 0.82/0.60 s and multiple working modes. Overall, this work showcases a prospective design pathway for the development of next‐generation ultrafast‐switching, and energy‐efficient intelligent windows. Through innovative molecular design and advanced device optimization, a high‐performance electrochromic device is achieved, demonstrating high transparency, rapid color‐switching, and excellent stability. In conjunction with the creation of a thermoresponsive gel electrolyte, an electro‐ and thermochromic device is realized, exhibiting flame‐retardant properties and energy‐saving characteristics. Such an advanced device equips smart windows with energy efficiency, privacy protection, and decorative enhancements.