Photoinitiated radical polymerization of some substituted tetrahydrophthalimido and maleimidophenyl methacrylates

The photopolymerization of some substituted tetrahydrophthalimido and 4‐(maleimido)phenyl methacrylates in N,N‐dimethylformamide solutions was investigated by photo‐differential scanning calorimetry at ambient temperature. Auto‐acceleration of photopolymerization and the formation of cross‐linked pr...

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Veröffentlicht in:	Polymer international 2004-01, Vol.53 (1), p.27-32
Hauptverfasser:	Gryshchuk, LYu, Vretik, LO, Syromyatnikov, VG, Novikova, OO, Paskal, LP, Voytekunas, VYu, Abadie, MJM
Format:	Artikel
Sprache:	eng
Schlagworte:	4-(maleimido)phenyl methacrylate Applied sciences Exact sciences and technology photopolymerization Physicochemistry of polymers Polymer industry, paints, wood Technology of polymers tetrahydrophthalimidophenyl methacrylate
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Beschreibung
Zusammenfassung:	The photopolymerization of some substituted tetrahydrophthalimido and 4‐(maleimido)phenyl methacrylates in N,N‐dimethylformamide solutions was investigated by photo‐differential scanning calorimetry at ambient temperature. Auto‐acceleration of photopolymerization and the formation of cross‐linked products were observed as a result of temperature increases up to 60–80 °C. Substituted 4‐(maleimido)phenyl methacrylates demonstrated higher cross‐linking abilities at elevated temperatures than tetrahydrophthalimidophenyl methacrylates. Copyright © 2003 Society of Chemical Industry
ISSN:	0959-8103 1097-0126
DOI:	10.1002/pi.1382