Physical speciation of arsenic, mercury, lead, cadmium and nickel in inhalable atmospheric particles

Physical speciation of metals (size distribution) in airborne particles has been studied in 24 areas of Seville (Spain). Urban particles were collected with a high-volume sampling systems equipped with cascade impactor and PM 10 inlets. Particle samples were analysed by acid digestion assisted by microwave heating using a HNO 3:HClO 4 (3:1,v/v) mixture. Arsenic was determined by hydride generation atomic absorption spectrometry (AAS), mercury by AAS with cold vapour atomisation and inductively coupled plasma atomic emission spectrometry was employed to determine lead, cadmium and nickel. Analyses of PM 10 samples revealed that the highest mean concentration was obtained for Pb, 14.04 ng m −3. Values of 3.42 and 2.88 ng m −3 were obtained for As and Ni, respectively. The lowest concentrations were obtained for Cd, 0.49 ng m −3, and especially for Hg, 0.07 ng m −3. Their physical speciation in air concentrations (ng m −3) showed that the toxic elements As and Pb were accumulated in the fine particles of