Traceability of Croatian extra virgin olive oils to the provenance soils by multielement and carbon isotope composition and chemometrics

[Display omitted] •Soil geochemical fingerprints influence transfer and elemental composition of EVOO.•Direct link between elements in provenance soil and EVOO was proven.•Multielement and C isotopic composition can be used for authentication of EVOO. A capacity to determine the provenance of high-value food products is of high scientific and economic interest. With the aim to develop a tool for geographical traceability of Croatian extra virgin olive oils (EVOO), multielement composition and 13C/12C isotope ratio in EVOO as well as the geochemistry of the associated soils were analysed in samples collected from three regions along the Croatian Adriatic coast. Soil geochemistry was shown to influence the transfer and elemental composition of EVOO. The most discriminating variables to distinguish EVOO from different regions were S, Mo, Rb, Mg, Pb, Mn, Sn, K, V and δ13C. The predictive models achieved high sensitivity and specificity, especially when carbon isotope composition was added. The results suggest that interregional geographical traceability of Croatian EVOO is possible based on matching their multielement composition with that of the soils in the provenance area.