Development of a quantitative theory of polycondensation

This review presents the first systematic treatment of the voluminous literature on the theory of polycondensation. Processes for obtaining homo- and copolymers with linear and branched macromolecules are considered. Emphasis is on a thorough discussion of various polycondensation models, and the me...

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Veröffentlicht in:	Progress in polymer science 2004-06, Vol.29 (6), p.563-633
Hauptverfasser:	Kuchanov, S., Slot, H., Stroeks, A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Batch and continuous reactors Composition distribution Gelation Kinetic Kinetic models Linear and branched polycondensation Macrocyclization reactions Molecular weight distribution Sequence distribution Substitution effects The Flory principle Thermodynamic and statistical methods
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Beschreibung
Zusammenfassung:	This review presents the first systematic treatment of the voluminous literature on the theory of polycondensation. Processes for obtaining homo- and copolymers with linear and branched macromolecules are considered. Emphasis is on a thorough discussion of various polycondensation models, and the methods of their solution for the calculation of the statistical characteristics of the chemical structure of polymers. The effects on these characteristics of the process modes for thermodynamically and kinetically controlled regimes of a polycondensation are analyzed in detail.
ISSN:	0079-6700 1873-1619
DOI:	10.1016/j.progpolymsci.2004.02.001