Germanium photopatterning via poly(cyclogermapentene)s

Germanium photopatterning via poly(cyclogermapentene)s

A series of air-stable poly(cyclogermapentene)s were prepared the dehydrocoupling of 1,1-dihydrocyclogermapentene monomers. Exposure of the resulting polygermanes to UV light led to elimination of organobutadiene from the polymer side chains and deposition of germanium metal. Overall, this study int...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-06, Vol.59 (45), p.6849-6852
Hauptverfasser: Medroa Del Pino, William, Ferero Pico, Andres A, Gupta, Manisha, Rivard, Eric
Format: Artikel
Sprache:eng
Schlagworte:
Germanium
Optoelectronics
Ultraviolet radiation
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Zusammenfassung:A series of air-stable poly(cyclogermapentene)s were prepared the dehydrocoupling of 1,1-dihydrocyclogermapentene monomers. Exposure of the resulting polygermanes to UV light led to elimination of organobutadiene from the polymer side chains and deposition of germanium metal. Overall, this study introduces a mild way to obtain patterns of semiconducting Ge for optoelectronic applications.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc01708g