The Crucial Role of Electrode Potential of a Working Anode in Dictating the Structural Evolution of Solid Electrolyte Interphase
The performance of rechargeable lithium (Li) batteries is highly correlated with the structure of solid electrolyte interphase (SEI). The properties of a working anode are vital factors in determining the structure of SEI; however, the correspondingly poor understanding hinders the rational regulati...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2022-10, Vol.61 (42), p.e202208743-n/a |
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| creator | Sun, Shu‐Yu Yao, Nao Jin, Cheng‐Bin Xie, Jin Li, Xi‐Yao Zhou, Ming‐Yue Chen, Xiang Li, Bo‐Quan Zhang, Xue‐Qiang Zhang, Qiang |
| description | The performance of rechargeable lithium (Li) batteries is highly correlated with the structure of solid electrolyte interphase (SEI). The properties of a working anode are vital factors in determining the structure of SEI; however, the correspondingly poor understanding hinders the rational regulation of SEI. Herein, the electrode potential and anode material, two critical properties of an anode, in dictating the structural evolution of SEI were investigated theoretically and experimentally. The anode potential is identified as a crucial role in dictating the SEI structure. The anode potential determines the reduction products in the electrolyte, ultimately giving rise to the mosaic and bilayer SEI structure at high and low potential, respectively. In contrast, the anode material does not cause a significant change in the SEI structure. This work discloses the crucial role of electrode potential in dictating SEI structure and provides rational guidance to regulate SEI structure.
The role of electrode potential and anode material, two critical properties of a working anode, in dictating the structural evolution of solid electrolyte interphase (SEI) was investigated theoretically and experimentally, which provides rational guidance to regulate SEI structure. |
| doi_str_mv | 10.1002/anie.202208743 |
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The role of electrode potential and anode material, two critical properties of a working anode, in dictating the structural evolution of solid electrolyte interphase (SEI) was investigated theoretically and experimentally, which provides rational guidance to regulate SEI structure.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202208743</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Anode/Electrolyte Interface ; Anodes ; Electrode materials ; Electrode Potential ; Electrode potentials ; Electrodes ; electrolytes ; Evolution ; Interphase ; Lithium ; Lithium Batteries ; Rechargeable batteries ; Solid Electrolyte Interphase ; Solid electrolytes ; Structure Evolution</subject><ispartof>Angewandte Chemie International Edition, 2022-10, Vol.61 (42), p.e202208743-n/a</ispartof><rights>2022 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3833-602fd043ec32feaef9f60cc63fce99ad29e34491733c40d1a8e0fedcc4ebf32d3</citedby><cites>FETCH-LOGICAL-c3833-602fd043ec32feaef9f60cc63fce99ad29e34491733c40d1a8e0fedcc4ebf32d3</cites><orcidid>0000-0002-3929-1541</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202208743$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202208743$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Sun, Shu‐Yu</creatorcontrib><creatorcontrib>Yao, Nao</creatorcontrib><creatorcontrib>Jin, Cheng‐Bin</creatorcontrib><creatorcontrib>Xie, Jin</creatorcontrib><creatorcontrib>Li, Xi‐Yao</creatorcontrib><creatorcontrib>Zhou, Ming‐Yue</creatorcontrib><creatorcontrib>Chen, Xiang</creatorcontrib><creatorcontrib>Li, Bo‐Quan</creatorcontrib><creatorcontrib>Zhang, Xue‐Qiang</creatorcontrib><creatorcontrib>Zhang, Qiang</creatorcontrib><title>The Crucial Role of Electrode Potential of a Working Anode in Dictating the Structural Evolution of Solid Electrolyte Interphase</title><title>Angewandte Chemie International Edition</title><description>The performance of rechargeable lithium (Li) batteries is highly correlated with the structure of solid electrolyte interphase (SEI). The properties of a working anode are vital factors in determining the structure of SEI; however, the correspondingly poor understanding hinders the rational regulation of SEI. Herein, the electrode potential and anode material, two critical properties of an anode, in dictating the structural evolution of SEI were investigated theoretically and experimentally. The anode potential is identified as a crucial role in dictating the SEI structure. The anode potential determines the reduction products in the electrolyte, ultimately giving rise to the mosaic and bilayer SEI structure at high and low potential, respectively. In contrast, the anode material does not cause a significant change in the SEI structure. This work discloses the crucial role of electrode potential in dictating SEI structure and provides rational guidance to regulate SEI structure.
The role of electrode potential and anode material, two critical properties of a working anode, in dictating the structural evolution of solid electrolyte interphase (SEI) was investigated theoretically and experimentally, which provides rational guidance to regulate SEI structure.</description><subject>Anode/Electrolyte Interface</subject><subject>Anodes</subject><subject>Electrode materials</subject><subject>Electrode Potential</subject><subject>Electrode potentials</subject><subject>Electrodes</subject><subject>electrolytes</subject><subject>Evolution</subject><subject>Interphase</subject><subject>Lithium</subject><subject>Lithium Batteries</subject><subject>Rechargeable batteries</subject><subject>Solid Electrolyte Interphase</subject><subject>Solid electrolytes</subject><subject>Structure Evolution</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFkctLAzEQxhdRUKtXzwEvXlrz2O5mj6VWLRQVH3hcYnaiqWlSk6zSm3-6WeoDvPQ0w8zv-5jhy7IjggcEY3oqrIYBxZRiXuZsK9sjQ0r6rCzZdupzxvolH5LdbD-EeeI5x8Ve9nn_AmjsW6mFQbfOAHIKTQzI6F0D6MZFsLHbpbFAj86_avuMRrZbaovOtIwidqOYfO5iMoqtT_jk3Zk2amc74Z0zuvlxNasIaGoj-OWLCHCQ7ShhAhx-1172cD65H1_2Z9cX0_Fo1peMp9MLTFWDcwaSUQUCVKUKLGXBlISqEg2tgOV5RUrGZI4bIjhgBY2UOTwpRhvWy07Wvkvv3loIsV7oIMEYYcG1oaackKrMC443oyWmhGM65Ak9_ofOXetteiRRlFGOy4okarCmpHcheFD10uuF8Kua4LrLru6yq3-zS4JqLfjQBlYb6Hp0NZ38ab8AVQiewQ</recordid><startdate>20221017</startdate><enddate>20221017</enddate><creator>Sun, Shu‐Yu</creator><creator>Yao, Nao</creator><creator>Jin, Cheng‐Bin</creator><creator>Xie, Jin</creator><creator>Li, Xi‐Yao</creator><creator>Zhou, Ming‐Yue</creator><creator>Chen, Xiang</creator><creator>Li, Bo‐Quan</creator><creator>Zhang, Xue‐Qiang</creator><creator>Zhang, Qiang</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0002-3929-1541</orcidid></search><sort><creationdate>20221017</creationdate><title>The Crucial Role of Electrode Potential of a Working Anode in Dictating the Structural Evolution of Solid Electrolyte Interphase</title><author>Sun, Shu‐Yu ; Yao, Nao ; Jin, Cheng‐Bin ; Xie, Jin ; Li, Xi‐Yao ; Zhou, Ming‐Yue ; Chen, Xiang ; Li, Bo‐Quan ; Zhang, Xue‐Qiang ; Zhang, Qiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3833-602fd043ec32feaef9f60cc63fce99ad29e34491733c40d1a8e0fedcc4ebf32d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Anode/Electrolyte Interface</topic><topic>Anodes</topic><topic>Electrode materials</topic><topic>Electrode Potential</topic><topic>Electrode potentials</topic><topic>Electrodes</topic><topic>electrolytes</topic><topic>Evolution</topic><topic>Interphase</topic><topic>Lithium</topic><topic>Lithium Batteries</topic><topic>Rechargeable batteries</topic><topic>Solid Electrolyte Interphase</topic><topic>Solid electrolytes</topic><topic>Structure Evolution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Shu‐Yu</creatorcontrib><creatorcontrib>Yao, Nao</creatorcontrib><creatorcontrib>Jin, Cheng‐Bin</creatorcontrib><creatorcontrib>Xie, Jin</creatorcontrib><creatorcontrib>Li, Xi‐Yao</creatorcontrib><creatorcontrib>Zhou, Ming‐Yue</creatorcontrib><creatorcontrib>Chen, Xiang</creatorcontrib><creatorcontrib>Li, Bo‐Quan</creatorcontrib><creatorcontrib>Zhang, Xue‐Qiang</creatorcontrib><creatorcontrib>Zhang, Qiang</creatorcontrib><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Shu‐Yu</au><au>Yao, Nao</au><au>Jin, Cheng‐Bin</au><au>Xie, Jin</au><au>Li, Xi‐Yao</au><au>Zhou, Ming‐Yue</au><au>Chen, Xiang</au><au>Li, Bo‐Quan</au><au>Zhang, Xue‐Qiang</au><au>Zhang, Qiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Crucial Role of Electrode Potential of a Working Anode in Dictating the Structural Evolution of Solid Electrolyte Interphase</atitle><jtitle>Angewandte Chemie International Edition</jtitle><date>2022-10-17</date><risdate>2022</risdate><volume>61</volume><issue>42</issue><spage>e202208743</spage><epage>n/a</epage><pages>e202208743-n/a</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>The performance of rechargeable lithium (Li) batteries is highly correlated with the structure of solid electrolyte interphase (SEI). The properties of a working anode are vital factors in determining the structure of SEI; however, the correspondingly poor understanding hinders the rational regulation of SEI. Herein, the electrode potential and anode material, two critical properties of an anode, in dictating the structural evolution of SEI were investigated theoretically and experimentally. The anode potential is identified as a crucial role in dictating the SEI structure. The anode potential determines the reduction products in the electrolyte, ultimately giving rise to the mosaic and bilayer SEI structure at high and low potential, respectively. In contrast, the anode material does not cause a significant change in the SEI structure. This work discloses the crucial role of electrode potential in dictating SEI structure and provides rational guidance to regulate SEI structure.
The role of electrode potential and anode material, two critical properties of a working anode, in dictating the structural evolution of solid electrolyte interphase (SEI) was investigated theoretically and experimentally, which provides rational guidance to regulate SEI structure.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/anie.202208743</doi><tpages>8</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-3929-1541</orcidid></addata></record> |
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| subjects | Anode/Electrolyte Interface Anodes Electrode materials Electrode Potential Electrode potentials Electrodes electrolytes Evolution Interphase Lithium Lithium Batteries Rechargeable batteries Solid Electrolyte Interphase Solid electrolytes Structure Evolution |
| title | The Crucial Role of Electrode Potential of a Working Anode in Dictating the Structural Evolution of Solid Electrolyte Interphase |
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