Borenium-ion-catalyzed hydrogenation of arenes
Non-metal-catalyzed hydrogenation of arenes represents a sustainable and environment-friendly approach for the synthesis of cyclohexane derivatives. Herein, we report the development of a borenium-ion catalyst system which can hydrogenate a number of monocyclic arenes. Additionally, this metal-free...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2023-05, Vol.59 (39), p.5847-5849 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Non-metal-catalyzed hydrogenation of arenes represents a sustainable and environment-friendly approach for the synthesis of cyclohexane derivatives. Herein, we report the development of a borenium-ion catalyst system which can hydrogenate a number of monocyclic arenes. Additionally, this metal-free catalytic system allows selective partial or full hydrogenation of naphthalene and anthracene by modification of the reaction conditions. Our mechanism studies suggest that the borenium-arene-mediated H
2
splitting takes place before the rate-limiting step and the hydride transfer between the resulting neutral borane and protonated arene is likely the rate-limiting step in the catalytic process.
Metal-free hydrogenation of arenes was achieved by using a borenium ion as the catalyst. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/d3cc01303k |