Simultaneous Hydrogen Bonds with Different Binding Modes: The Acceptor “Rules” but the Donor “Chooses”

Invited for the cover of this issue is the group of Cristina Trujillo at Trinity College Dublin and the University of Manchester. The image depicts a market run by hydrogen bond acceptors in which hydrogen‐bond‐donor “customers” are choosing their preferred binding mode “vegetable”. Read the full text of the article at 10.1002/chem.202203577. “π–π interactions were a major obstacle for us when trying to characterise the different types of binding modes as most of our donors and acceptors included phenyl rings.” This and more about the story behind the front cover can be found in the article at 10.1002/chem.202203577).