Noble-Metal-Free FeMn-N-C catalyst for efficient oxygen reduction reaction in both alkaline and acidic media

[Display omitted] The oxygen reduction reaction (ORR) is important cathodic reaction running in several electrochemical energy conversion devices. It is still difficult to develop non-precious nanocatalysts for ORR that have high activity and increased durability for practical application. Herein, bimetallic FeMn(mIm)-N-C composite incorporated with Fe and Mn via an encapsulation-ligand exchange technique is prepared and established as an efficient ORR catalyst. The results reveal that FeMn(mIm)-N-C shows outstanding ORR performance with E1/2 of 0.861 V and 0.778 V in alkaline and acid solutions, along with robust durability. Additionally, the assembled Zn-Air batteries (ZAB) and proton exchange membrane fuel cells (PEMFCs) both have exceptional power densities and show promise for long-term stability compared to 20% Pt/C. The present work provides a useful strategy for designing and synthesizing a reliable low-cost and high-efficient electrocatalysts for energy conversion and storage.