Pd-catalysed cross-coupling of allenylic carbonates with gem -diborylalkanes: efficient synthesis of isoprenylboronates

A simple and novel Pd-catalysed cross-coupling reaction of allenylic carbonates with different -diborylalkanes was developed. Under mild reaction conditions, synthetically useful and versatile isoprenylboronates could be obtained selectively in moderate to high yields. Furthermore, the utility of th...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic & biomolecular chemistry 2023-04, Vol.21 (16), p.3355-3359
Hauptverfasser: Ma, Xin-Ru, Zhong, Qin, Zhang, Qian-Cheng, Hu, Hua-Xing, Yu, Ma-Hong, Zhao, Jian
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A simple and novel Pd-catalysed cross-coupling reaction of allenylic carbonates with different -diborylalkanes was developed. Under mild reaction conditions, synthetically useful and versatile isoprenylboronates could be obtained selectively in moderate to high yields. Furthermore, the utility of the novel isoprenylboronate is demonstrated through isoprenylboration and homologation.
ISSN:1477-0520
1477-0539
DOI:10.1039/d3ob00109a