New universal relationships for surface tension and vaporization enthalpy of non-associated liquids

The methodology of thermodynamic similarity has been used to study the relation between the surface tension of a liquid and the vaporization enthalpy calculated per unit volume of the liquid phase. Simple reliable relationships that do not contain substance dependent parameters have been found. A ne...

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Veröffentlicht in:Fluid phase equilibria 2003-08, Vol.211 (1), p.75-83
1. Verfasser: Faizullin, Mars Z
Format: Artikel
Sprache:eng
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Zusammenfassung:The methodology of thermodynamic similarity has been used to study the relation between the surface tension of a liquid and the vaporization enthalpy calculated per unit volume of the liquid phase. Simple reliable relationships that do not contain substance dependent parameters have been found. A new universal one-parameter relationship for the temperature dependence of the vaporization enthalpy has been suggested. The results of calculations with the use of these relationships are compared with experimental data.
ISSN:0378-3812
1879-0224
DOI:10.1016/S0378-3812(03)00127-4