Synthesis of bagasse nanocellulose-filled composite polyurethane xerogel for the efficient adsorption of Rhodamine-B dye from aqueous solution: investigation of adsorption parameters
In this study, polyurethane (PU)-based xerogels were synthesized by using the biobased polyol derived from chaulmoogra seed oil. These polyol was used for the preparation of PU xerogels using methylene diphenyl diisocyanate hard segment and polyethylene glycol (PEG6000) as soft segment with 1,4-diaz...
Gespeichert in:
| Veröffentlicht in: | The European physical journal. E, Soft matter and biological physics Soft matter and biological physics, 2023-04, Vol.46 (4), p.23-23, Article 23 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 23 |
|---|---|
| container_issue | 4 |
| container_start_page | 23 |
| container_title | The European physical journal. E, Soft matter and biological physics |
| container_volume | 46 |
| creator | Vijayan, Jyothy G. Niranjana Prabhu, T. Jineesh, A. G. Pal, Kaushik Chakroborty, Subhendu |
| description | In this study, polyurethane (PU)-based xerogels were synthesized by using the biobased polyol derived from chaulmoogra seed oil. These polyol was used for the preparation of PU xerogels using methylene diphenyl diisocyanate hard segment and polyethylene glycol (PEG6000) as soft segment with 1,4-diazabicyclo[2, 2, 2]octane as catalyst. Tetrahydrofuran, acetonitrile and dimethyl sulfoxide were used as the solvents. Nanocellulose (5 wt %) prepared from bagasse were added as filler, and the obtained composite xerogels were evaluated for chemical stability. The prepared samples were also characterized by using SEM and FTIR. Waste sugarcane bagasse nanocellulose proved as a cheap reinforcer in the xerogel synthesis and for the adsorption of Rhodamine-B dye from the aqueous solution. The factors that affect the adsorption process have been studied including the quantity of the adsorbent (0.02–0.06 g), pH (6–12), temperature (30–50) and time (30–90). Central composite design for four variables and three levels with response surface methodology has been used to get second-order polynomial equation for the percentage dye removal. RSM was confirmed by the measurement of analysis of variance. Increase in the pH and quantity of the adsorbent was found to increase the sorption capacities of the xerogel (NC-PUXe) towards rhodamine B, maximum adsorption.
Graphical abstract |
| doi_str_mv | 10.1140/epje/s10189-023-00278-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2792903837</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2792957863</sourcerecordid><originalsourceid>FETCH-LOGICAL-c390t-29465a8f5ac29395d913e8010a905758dfa2130d8d06f73ff6adfad1c1399ebd3</originalsourceid><addsrcrecordid>eNqFkctu1DAUhi0Eohd4BbDEhk2oL5PEZgcVBaRKSFwkdpYnPp7xKLGDT4KYF-P5cEhbEBtWtuzvfPrtn5CnnL3gfMMuYDzABXLGla6YkBVjolVVe4-ccqFFpXT99f7dfsNPyBnigTFWZuVDciIbretNq0_Jz0_HOO0BA9Lk6dbuLCLQaGPqoO_nPiFUPvQ9ONqlYUwYJqBj6o9zhmlvI9AfkNMOeupTpsVEwfvQBYgTtQ5THqeQ4uL-uE_ODiFC9Zq6I1Cf00DttxnSjBRTPy_gSxrid8Ap7Ozt3F-W0WY7wAQZH5EH3vYIj2_Wc_Ll6s3ny3fV9Ye37y9fXVed1GyqhN40tVW-tp3QUtdOcwmKcWY1q9taOW8Fl8wpxxrfSu8bW44c77jUGrZOnpPnq3fMqUTFyQwBl58pLy-5jWi10Ewq2Rb02T_oIc05lnQrVbeqkYVqV6rLCTGDN2MOg81Hw5lZqjVLtWat1pRqze9qzeJ_cuOftwO4u7nbLgugVgDLVdxB_hPgf-5fJ524rQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2792957863</pqid></control><display><type>article</type><title>Synthesis of bagasse nanocellulose-filled composite polyurethane xerogel for the efficient adsorption of Rhodamine-B dye from aqueous solution: investigation of adsorption parameters</title><source>SpringerLink Journals - AutoHoldings</source><creator>Vijayan, Jyothy G. ; Niranjana Prabhu, T. ; Jineesh, A. G. ; Pal, Kaushik ; Chakroborty, Subhendu</creator><creatorcontrib>Vijayan, Jyothy G. ; Niranjana Prabhu, T. ; Jineesh, A. G. ; Pal, Kaushik ; Chakroborty, Subhendu</creatorcontrib><description>In this study, polyurethane (PU)-based xerogels were synthesized by using the biobased polyol derived from chaulmoogra seed oil. These polyol was used for the preparation of PU xerogels using methylene diphenyl diisocyanate hard segment and polyethylene glycol (PEG6000) as soft segment with 1,4-diazabicyclo[2, 2, 2]octane as catalyst. Tetrahydrofuran, acetonitrile and dimethyl sulfoxide were used as the solvents. Nanocellulose (5 wt %) prepared from bagasse were added as filler, and the obtained composite xerogels were evaluated for chemical stability. The prepared samples were also characterized by using SEM and FTIR. Waste sugarcane bagasse nanocellulose proved as a cheap reinforcer in the xerogel synthesis and for the adsorption of Rhodamine-B dye from the aqueous solution. The factors that affect the adsorption process have been studied including the quantity of the adsorbent (0.02–0.06 g), pH (6–12), temperature (30–50) and time (30–90). Central composite design for four variables and three levels with response surface methodology has been used to get second-order polynomial equation for the percentage dye removal. RSM was confirmed by the measurement of analysis of variance. Increase in the pH and quantity of the adsorbent was found to increase the sorption capacities of the xerogel (NC-PUXe) towards rhodamine B, maximum adsorption.
Graphical abstract</description><identifier>ISSN: 1292-8941</identifier><identifier>EISSN: 1292-895X</identifier><identifier>DOI: 10.1140/epje/s10189-023-00278-7</identifier><identifier>PMID: 36995479</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Acetonitrile ; Adsorbents ; Adsorption ; Aqueous solutions ; Bagasse ; Biological and Medical Physics ; Biophysics ; Complex Fluids and Microfluidics ; Complex Systems ; Condensed matter physics ; Diisocyanates ; Dimethyl sulfoxide ; Dyes ; Nanotechnology ; Novel Molecular Materials and Devices from Functional Soft Matter ; Physics ; Physics and Astronomy ; Polyethylene glycol ; Polymer Sciences ; Polynomials ; Polyurethane resins ; Regular Article - Soft Matter ; Response surface methodology ; Rhodamine ; Segments ; Skeletal composites ; Soft and Granular Matter ; Stability analysis ; Sugarcane ; Surfaces and Interfaces ; Synthesis ; Tetrahydrofuran ; Thin Films ; Variance analysis ; Xerogels</subject><ispartof>The European physical journal. E, Soft matter and biological physics, 2023-04, Vol.46 (4), p.23-23, Article 23</ispartof><rights>The Author(s), under exclusive licence to EDP Sciences, SIF and Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2023. The Author(s), under exclusive licence to EDP Sciences, SIF and Springer-Verlag GmbH Germany, part of Springer Nature.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c390t-29465a8f5ac29395d913e8010a905758dfa2130d8d06f73ff6adfad1c1399ebd3</citedby><cites>FETCH-LOGICAL-c390t-29465a8f5ac29395d913e8010a905758dfa2130d8d06f73ff6adfad1c1399ebd3</cites><orcidid>0000-0002-9313-6497</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1140/epje/s10189-023-00278-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1140/epje/s10189-023-00278-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36995479$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Vijayan, Jyothy G.</creatorcontrib><creatorcontrib>Niranjana Prabhu, T.</creatorcontrib><creatorcontrib>Jineesh, A. G.</creatorcontrib><creatorcontrib>Pal, Kaushik</creatorcontrib><creatorcontrib>Chakroborty, Subhendu</creatorcontrib><title>Synthesis of bagasse nanocellulose-filled composite polyurethane xerogel for the efficient adsorption of Rhodamine-B dye from aqueous solution: investigation of adsorption parameters</title><title>The European physical journal. E, Soft matter and biological physics</title><addtitle>Eur. Phys. J. E</addtitle><addtitle>Eur Phys J E Soft Matter</addtitle><description>In this study, polyurethane (PU)-based xerogels were synthesized by using the biobased polyol derived from chaulmoogra seed oil. These polyol was used for the preparation of PU xerogels using methylene diphenyl diisocyanate hard segment and polyethylene glycol (PEG6000) as soft segment with 1,4-diazabicyclo[2, 2, 2]octane as catalyst. Tetrahydrofuran, acetonitrile and dimethyl sulfoxide were used as the solvents. Nanocellulose (5 wt %) prepared from bagasse were added as filler, and the obtained composite xerogels were evaluated for chemical stability. The prepared samples were also characterized by using SEM and FTIR. Waste sugarcane bagasse nanocellulose proved as a cheap reinforcer in the xerogel synthesis and for the adsorption of Rhodamine-B dye from the aqueous solution. The factors that affect the adsorption process have been studied including the quantity of the adsorbent (0.02–0.06 g), pH (6–12), temperature (30–50) and time (30–90). Central composite design for four variables and three levels with response surface methodology has been used to get second-order polynomial equation for the percentage dye removal. RSM was confirmed by the measurement of analysis of variance. Increase in the pH and quantity of the adsorbent was found to increase the sorption capacities of the xerogel (NC-PUXe) towards rhodamine B, maximum adsorption.
Graphical abstract</description><subject>Acetonitrile</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Bagasse</subject><subject>Biological and Medical Physics</subject><subject>Biophysics</subject><subject>Complex Fluids and Microfluidics</subject><subject>Complex Systems</subject><subject>Condensed matter physics</subject><subject>Diisocyanates</subject><subject>Dimethyl sulfoxide</subject><subject>Dyes</subject><subject>Nanotechnology</subject><subject>Novel Molecular Materials and Devices from Functional Soft Matter</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Polyethylene glycol</subject><subject>Polymer Sciences</subject><subject>Polynomials</subject><subject>Polyurethane resins</subject><subject>Regular Article - Soft Matter</subject><subject>Response surface methodology</subject><subject>Rhodamine</subject><subject>Segments</subject><subject>Skeletal composites</subject><subject>Soft and Granular Matter</subject><subject>Stability analysis</subject><subject>Sugarcane</subject><subject>Surfaces and Interfaces</subject><subject>Synthesis</subject><subject>Tetrahydrofuran</subject><subject>Thin Films</subject><subject>Variance analysis</subject><subject>Xerogels</subject><issn>1292-8941</issn><issn>1292-895X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkctu1DAUhi0Eohd4BbDEhk2oL5PEZgcVBaRKSFwkdpYnPp7xKLGDT4KYF-P5cEhbEBtWtuzvfPrtn5CnnL3gfMMuYDzABXLGla6YkBVjolVVe4-ccqFFpXT99f7dfsNPyBnigTFWZuVDciIbretNq0_Jz0_HOO0BA9Lk6dbuLCLQaGPqoO_nPiFUPvQ9ONqlYUwYJqBj6o9zhmlvI9AfkNMOeupTpsVEwfvQBYgTtQ5THqeQ4uL-uE_ODiFC9Zq6I1Cf00DttxnSjBRTPy_gSxrid8Ap7Ozt3F-W0WY7wAQZH5EH3vYIj2_Wc_Ll6s3ny3fV9Ye37y9fXVed1GyqhN40tVW-tp3QUtdOcwmKcWY1q9taOW8Fl8wpxxrfSu8bW44c77jUGrZOnpPnq3fMqUTFyQwBl58pLy-5jWi10Ewq2Rb02T_oIc05lnQrVbeqkYVqV6rLCTGDN2MOg81Hw5lZqjVLtWat1pRqze9qzeJ_cuOftwO4u7nbLgugVgDLVdxB_hPgf-5fJ524rQ</recordid><startdate>20230401</startdate><enddate>20230401</enddate><creator>Vijayan, Jyothy G.</creator><creator>Niranjana Prabhu, T.</creator><creator>Jineesh, A. G.</creator><creator>Pal, Kaushik</creator><creator>Chakroborty, Subhendu</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-9313-6497</orcidid></search><sort><creationdate>20230401</creationdate><title>Synthesis of bagasse nanocellulose-filled composite polyurethane xerogel for the efficient adsorption of Rhodamine-B dye from aqueous solution: investigation of adsorption parameters</title><author>Vijayan, Jyothy G. ; Niranjana Prabhu, T. ; Jineesh, A. G. ; Pal, Kaushik ; Chakroborty, Subhendu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c390t-29465a8f5ac29395d913e8010a905758dfa2130d8d06f73ff6adfad1c1399ebd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Acetonitrile</topic><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Bagasse</topic><topic>Biological and Medical Physics</topic><topic>Biophysics</topic><topic>Complex Fluids and Microfluidics</topic><topic>Complex Systems</topic><topic>Condensed matter physics</topic><topic>Diisocyanates</topic><topic>Dimethyl sulfoxide</topic><topic>Dyes</topic><topic>Nanotechnology</topic><topic>Novel Molecular Materials and Devices from Functional Soft Matter</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Polyethylene glycol</topic><topic>Polymer Sciences</topic><topic>Polynomials</topic><topic>Polyurethane resins</topic><topic>Regular Article - Soft Matter</topic><topic>Response surface methodology</topic><topic>Rhodamine</topic><topic>Segments</topic><topic>Skeletal composites</topic><topic>Soft and Granular Matter</topic><topic>Stability analysis</topic><topic>Sugarcane</topic><topic>Surfaces and Interfaces</topic><topic>Synthesis</topic><topic>Tetrahydrofuran</topic><topic>Thin Films</topic><topic>Variance analysis</topic><topic>Xerogels</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vijayan, Jyothy G.</creatorcontrib><creatorcontrib>Niranjana Prabhu, T.</creatorcontrib><creatorcontrib>Jineesh, A. G.</creatorcontrib><creatorcontrib>Pal, Kaushik</creatorcontrib><creatorcontrib>Chakroborty, Subhendu</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>The European physical journal. E, Soft matter and biological physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vijayan, Jyothy G.</au><au>Niranjana Prabhu, T.</au><au>Jineesh, A. G.</au><au>Pal, Kaushik</au><au>Chakroborty, Subhendu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of bagasse nanocellulose-filled composite polyurethane xerogel for the efficient adsorption of Rhodamine-B dye from aqueous solution: investigation of adsorption parameters</atitle><jtitle>The European physical journal. E, Soft matter and biological physics</jtitle><stitle>Eur. Phys. J. E</stitle><addtitle>Eur Phys J E Soft Matter</addtitle><date>2023-04-01</date><risdate>2023</risdate><volume>46</volume><issue>4</issue><spage>23</spage><epage>23</epage><pages>23-23</pages><artnum>23</artnum><issn>1292-8941</issn><eissn>1292-895X</eissn><abstract>In this study, polyurethane (PU)-based xerogels were synthesized by using the biobased polyol derived from chaulmoogra seed oil. These polyol was used for the preparation of PU xerogels using methylene diphenyl diisocyanate hard segment and polyethylene glycol (PEG6000) as soft segment with 1,4-diazabicyclo[2, 2, 2]octane as catalyst. Tetrahydrofuran, acetonitrile and dimethyl sulfoxide were used as the solvents. Nanocellulose (5 wt %) prepared from bagasse were added as filler, and the obtained composite xerogels were evaluated for chemical stability. The prepared samples were also characterized by using SEM and FTIR. Waste sugarcane bagasse nanocellulose proved as a cheap reinforcer in the xerogel synthesis and for the adsorption of Rhodamine-B dye from the aqueous solution. The factors that affect the adsorption process have been studied including the quantity of the adsorbent (0.02–0.06 g), pH (6–12), temperature (30–50) and time (30–90). Central composite design for four variables and three levels with response surface methodology has been used to get second-order polynomial equation for the percentage dye removal. RSM was confirmed by the measurement of analysis of variance. Increase in the pH and quantity of the adsorbent was found to increase the sorption capacities of the xerogel (NC-PUXe) towards rhodamine B, maximum adsorption.
Graphical abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>36995479</pmid><doi>10.1140/epje/s10189-023-00278-7</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0002-9313-6497</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1292-8941 |
| ispartof | The European physical journal. E, Soft matter and biological physics, 2023-04, Vol.46 (4), p.23-23, Article 23 |
| issn | 1292-8941 1292-895X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2792903837 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Acetonitrile Adsorbents Adsorption Aqueous solutions Bagasse Biological and Medical Physics Biophysics Complex Fluids and Microfluidics Complex Systems Condensed matter physics Diisocyanates Dimethyl sulfoxide Dyes Nanotechnology Novel Molecular Materials and Devices from Functional Soft Matter Physics Physics and Astronomy Polyethylene glycol Polymer Sciences Polynomials Polyurethane resins Regular Article - Soft Matter Response surface methodology Rhodamine Segments Skeletal composites Soft and Granular Matter Stability analysis Sugarcane Surfaces and Interfaces Synthesis Tetrahydrofuran Thin Films Variance analysis Xerogels |
| title | Synthesis of bagasse nanocellulose-filled composite polyurethane xerogel for the efficient adsorption of Rhodamine-B dye from aqueous solution: investigation of adsorption parameters |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-29T00%3A41%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20bagasse%20nanocellulose-filled%20composite%20polyurethane%20xerogel%20for%20the%20efficient%20adsorption%20of%20Rhodamine-B%20dye%20from%20aqueous%20solution:%20investigation%20of%20adsorption%20parameters&rft.jtitle=The%20European%20physical%20journal.%20E,%20Soft%20matter%20and%20biological%20physics&rft.au=Vijayan,%20Jyothy%20G.&rft.date=2023-04-01&rft.volume=46&rft.issue=4&rft.spage=23&rft.epage=23&rft.pages=23-23&rft.artnum=23&rft.issn=1292-8941&rft.eissn=1292-895X&rft_id=info:doi/10.1140/epje/s10189-023-00278-7&rft_dat=%3Cproquest_cross%3E2792957863%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2792957863&rft_id=info:pmid/36995479&rfr_iscdi=true |