Electrical properties of AgI–Ag2O–V2O5–P2O5 glasses
Mixed conductive silver vanadate-phosphate glasses were prepared and their electrical properties were studied. Compositions of the glasses were characterized by parameters: x (AgI content) and r=[Ag2O]/[V2O5 + P2O5]. Total conductivity *st (x, r = constant) of a series of samples with fixed r values...
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Veröffentlicht in: | Solid state ionics 2003-02, Vol.157 (1-4), p.269-273 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Mixed conductive silver vanadate-phosphate glasses were prepared and their electrical properties were studied. Compositions of the glasses were characterized by parameters: x (AgI content) and r=[Ag2O]/[V2O5 + P2O5]. Total conductivity *st (x, r = constant) of a series of samples with fixed r values exhibited minima when plotted vs. x. The conductivity minima were accompanied by maxima of apparent activation energy Et (x, r=constant). The observed dependencies were attributed to the ion-polaron effect (IPE), i.e. to electrostatic attraction between mobile species: electrons (polarons) and Ag+ ions. |
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ISSN: | 0167-2738 |
DOI: | 10.1016/S0167-2738(02)00220-5 |