Functional materials contributing to the removal of chlorinated hydrocarbons from soil and groundwater: Classification and intrinsic chemical-biological removal mechanisms

Chlorinated hydrocarbons (CHs) are the main contaminants in soil and groundwater and have posed great challenge on the remediation of soil and ground water. Different remediation materials have been developed to deal with the environmental problems caused by CHs. Remediation materials can be classified into three main categories according to the corresponding technologies: adsorption materials, chemical reduction materials and bioaugmentation materials. In this paper, the classification and preparation of the three materials are briefly described in terms of synthesis and properties according to the different types. Then, a detailed review of the remediation mechanisms and applications of the different materials in soil and groundwater remediation is presented in relation to the various properties of the materials and the different challenges encountered in laboratory research or in the environmental application. The removal trends in different environments were found to be largely similar, which means that composite materials tend to be more effective in removing CHs in actual remediation. For instance, adsorbents were found to be effective when combined with other materials, due to the ability to take advantage of the respective strengths of both materials. The rapid removal of CHs while minimizing the impact of CHs on another material and the material itself on the environment. Finally, suggestions for the next research directions are given in conjunction with this paper. [Display omitted] •Materials for removal of chlorinated hydrocarbons were reviewed.•Materials are classified based on adsorption, chemical reduction and bioaugmentation.•The mechanism and application of different materials for the removal of CHs are summarized.•Future directions for the development of different types of materials are proposed.